Fred uses his influence with a business friend to obtain a job for Barney, who becomes a furniture repossessor. To the dismay of both, Barney's first assignment is to repossess Fred's television! Unwilling to betray his friend, Barney pays off Fred's delinquent television bill with his first paycheck.
A Hollyrock film company goes on location in Bedrock to film its new feature Monster From The Tar Pits, and gullible Fred is enlisted as stand-in for star Gary Granite. But Fred's real problems begin when Wilma and Betty audition for roles in the film and end up going ga-ga upon meeting movie stars Rock Pile and Wednesday Tuesday.
Roped into babysitting little Egbert, the child of a friend, Fred and Barney take the tot over to the pal Joe Rockhead's house to watch the fights on television. Egbert befriends Joe's pet runtosaurus and dresses the creature up in his baby clothes, which results in chaos when the pet - whom Fred and Barney mistake for the baby - escapes from the house and dashes up a tree.
To finance their dream of opening a pool hall, Fred and Barney visit the dinosaur racetrack where Fred bets his entire paycheck on a long shot. He tells Wilma that he has lost his check. When the long shot pays off, Fred and Barney are initially elated, but they quickly realize their problems are only beginning.
Barney decides to surprise Betty with a belated engagement ring, which he gives to Fred for safekeeping. But Wilma discovers the ring and assumes it is a gift for her. Not wanting to shatter her illusions, Fred decides to buy a second ring, but doesn't have the cash. He cons Barney into going several rounds with a boxing champ in order to win a $500 prize.
Fred's victory in The Loyal Order of Dinosaurs golf tournament is soured when club president Barney withholds his trophy for nonpayment of club dues. Fred retaliates by demanding that Barney return every item he has borrowed over the years. The stalemate continues until Wilma and Betty manage to bring their husbands back together.
With a burglar on the loose in Bedrock, Betty decides to take judo lessons to protect herself. When Wilma wants to take lesson also, Fred ridicules the idea, arguing that one glimpse of a burglar would send her running in fear. To prove his point, Fred poses as the burglar and sneaks into the Rubble household, on the same night the real criminal shows up.
Fred and Barney decide to treat their wives to a night out, at an amusement park. Fred cuts a song at a recording booth as a souvenir but misplaces the record. It is later discovered by a group of teens who pass it along to a deejay, and Fred is suddenly transformed into unwitting rock star "Hi-Fye."
Fred and Barney sign up for dance lessons at Arthur Quarry's so that they do not humiliate themselves at the charity ball. Their excuse that they have joined the volunteer fire department falls apart when Betty and Wilma realize that the all-stone town of Bedrock is fire proof. The wives then suspect that their husbands are slipping out to meet other women.
When he discovers a bag containing $86,000, Fred's dreams of being a wealthy man finally seem to be coming true. But the money has been stolen from the bank, so Wilma and Betty force Fred and Barney to return the money to the bank, and unwittingly set them up as the primary suspects! The wives set a trap for the real culprits and Fred ends up saving the day.
Jealous Fred's discovery of a love poem that was sent to Wilma prompts him to hire Bedrock's top detective Perry Gunite, to find out who the home-wrecking poet is. Gunite's investigation mistakenly points to Barney. Fred plans revenge against his friend until Wilma reminds her husband that he had written the poem himself years earlier during their courtship.
When industrial tycoon J.L. Gotrocks decides he wants to rub shoulders with the common people, dead-ringer Fred is hired to fill in for him in the board room. Fred savors his new lifestyle at the country club, but the plan begins to unravel when J.L. demonstrates little tolerance for the common folk.
Friend Gus Gravel invites the Flintstones and the Rubbles to his seaside hotel for an all-expense-paid vacation. But upon arriving, the four find that the hotel's planned "activities" seem more like work. Gus finally confesses that his entire hotel staff has just resigned on the eve of a huge convention.
When Wilma gets a letter from her mother saying that she is moving in with her favorite son-in-law and his wife, Fred begins refurbishing a dilapidated shack to house Mrs. Slaghoople. But soon Wilma learns that he mother was not referring to Fred, but her other daughter's husband. Fred is delighted, until he realizes how much he spent on the shack.
Through a publicity contest, Wilma and Betty win movie star Stoney Curtis (voiced by Tony Curtis) as a "slave boy" for a day. Jealous Fred works him unmercifully, until Stoney offers him a job as his stand-in for a new movie. Fred quits his job and prepares for life as a star, which, of course, is not all it is cracked up to be.
Hoping once again to strike it rich, Fred buys a circus. When the performers quit, Fred must put a show on himself with the help of Barney, Dino, and Hoppy, which he does successfully - so much that the performers return, and the former owner buys the big top back. To prove he is cured of get-rich-quick schemes, Fred passes up a chance to buy an oil well, which of course pays off.
Samantha and Darrin Stephens guest star from television's "Bewitched" (voiced by series star Elizabeth Montgomery and Dick York). Darrin goes boating, while Samantha joins the Flintstones and the Rubbles for a camping trip, which ends up pitting the men against the women. Aided by Samantha's witchcraft, the women manage to out-do the men at every turn.
Fred and Barney discover a visitor from another planet, the two-foot high, green Gazoo, who becomes their servant. An evening out at an expensive restaurant, supposedly with Gazoo treating, becomes a nightmare as the alien disappears, leaving the Flintstones and the Rubbles to wash dishes to pay for the food.
Bored by his company picnic, Fred slips away to take a nap, and awakens twenty years later to discover that Barney has become millionaire B.J. Rubble, and that Pebbles and Bamm-Bamm have gotten married. Upon entering Wilma who is now living alone through Barney's largesse, Fred really awakens and realizes it was all a dream.
When Fred is fired by Mr. Slate for fronting the other employees' list of grievances, he turns to pastry entrepreneur by selling Wilma's gravelberry pies. But soon the couple realize they are spending more in ingredients than they are making in profit. Ultimately, Wilma recoups the losses by selling the recipe to a supermarket tycoon.
A mix-up at the pharmacy gives Fred pills that turn him into an ape. Barney is the only one to see this short-lived effect, which makes him wonder about his own health. But when the two dads take their kids to the zoo and Fred ends up in the monkey cage after taking another pill, his problem becomes apparent to all.
Fred refuses to play the lead in the PTA show, "Romeorock and Julietstone," opposite Wilma, so she casts Barney instead. Feigning the mumps, Barney (who is terrible in the part) drops out, forcing Fred to take over. But then laryngitis causes Wilma to drop out, so Barney rushes back in, now playing Julietstone!
Fred is delighted to be invited onto Mr. Slate's yacht, until he learns that he is there to paint it. Asking the Rubbles to join them, the couples start having so much fun on board that they forget the paint job and fail to notice the yacht has broken free and is drifting. Slate charges Fred with mutiny and piracy, but Fred redeems himself when he rescues the visitors to an island (including Slate) from a volcano.
Fred is mistakenly granted membership to a swanky country club and asks Gazoo to turn him into a gentleman, a plan that involves taking ballet lessons, which makes him the laughingstock of the neighborhood. Finally Fred decides that he and Wilma should be themselves, and together they become the hit of the club.