交流戦ラストはリコ＆カエデVSチリ！四天王・チリとの対戦に緊張気味なリコ…。強敵を相手にニャローテとどう戦うのか―！？一方、迷子になったテラパゴスを探して校舎に向かったドット。そこで出会ったのは同じくオレンジアカデミーに通う生徒・ボタンだった…！
| Name | Type | Role | |
|---|---|---|---|
| Ryou Hirohashi | Guest Star | Penny | |
| Ayane Sakura | Guest Star | Ann's Dewott | |
| Mimi Maihane | Guest Star | Chalce | |
| Kotono Mitsuishi | Guest Star | Katy | |
| Taku Yashiro | Guest Star | Rika's Clodsire | |
| Yuuna Ogata | Guest Star | Ann | |
| Chiaki Kobayashi | Guest Star | Grusha | |
| Megumi Hayashibara | Guest Star | Liko's Floragato | |
| Sanae Kobayashi | Guest Star | Geeta | |
| Mitsuki Saiga | Guest Star | Rika | |
| Daiki Yamashita | Guest Star | Roy's Fuecoco | |
| Eri Kitamura | Guest Star | Nemona | |
| Eriko Matsui | Guest Star | Dendra | |
| Daisuke Namikawa | Guest Star | Dot's Quaxly |