Joining Jools are the Manic Street Preachers - no strangers to the show - to perform tracks from their new album Postcards from a Young Man, accompanied by a special guest performer. London-based Klaxons perform songs from their new album Surfing the Void, and the legendary Herb Alpert is in the studio to discuss his career. Producer/man about town Mark Ronson and his band the Business International play a couple of tunes from his upcoming Record Collection set, joined by a couple of special guest vocalists. Also in the studio, Queen Emily, who knew she would be a singer from the age of six, and at the age of 40 achieved a top-five place on America's Got Talent and subsequently a record deal with Tommy Couch's soul label Malaco.