Adrian Toomes becomes the Vulture to seek revenge on Norman Osborn, and Spider-Man must stop him. Meanwhile, Peter struggles to support Aunt May financially by selling photos of Spider-Man to J. Jonah Jameson.
An electrician named Max Dillon becomes the supervillain known as Electro after a freak accident and it's up to the Spectacular Spider-Man to stop his rampage. Meanwhile, Peter tries to tutor the popular Liz Allen.
While Peter Parker resists taking on the responsibility of helping Aunt May pay the bills, Montana the Big Man's Enforcer - becomes the stunning Shocker to fulfill his responsibility: eliminating the Spectacular Spider-Man.
Peter Parker and Harry Osborn try out for the football team -- and become a bit obsessed with going for the glory. Flint Marko, newly transformed into the Sandman, is out for glory too -- at the expense of our friendly neighborhood Spider-Man.
Peter Parker struggles to find a date and pay for the Fall Formal, while the Rhino, a new villain created by the Big Man, seeks revenge on Spider-Man. Spidey takes the fight to the Big Man, who has been secretly orchestrating the attacks.
Peter Parker and Mary Jane Watson go to the Midtown High Fall Formal. Meanwhile, Norman Osborn conducts a new experiment on himself, thus becoming the Green Goblin. Then, Green Goblin tries to take down L. Thompson Lincoln.
Tired of constantly being pushed around by others, the timid Otto Octavius has his robotic arms permanently attached to his back and becomes the deadly Doctor Octopus.
The Chameleon is out to blacken Spider-Man's name. The master of disguise loots the city while borrowing Spidey's look, forcing Peter Parker to get help from Black Cat.
Mysterio and Kraven join the ranks of the Sinister Six (including Sandman, Rhino, Vulture and Electro) in an attempt to capture Spider-Man once and for all.
Things seem to be going well for Peter Parker when he is invited to Flash Thompson's birthday party. Things change, however, when Sandman returns with a score to settle.
When aliens infect John Jameson with toxic spores, he begins to increase in size and strength. Seeing this as a perfect opportunity to capture Spider-Man, J. Jonah Jameson manipulates his son into becoming a super-hero.
Spider-Man encounters a group of super-villains, the New Enforcers, forcing him to battle Shocker, Ricohet and Ox. Meanwhile, Peter Parker's life isn't going much better.
In order to become the new Big Man, Hammerhead betrays Tombstone, Doctor Octopus and Silvermane. Now, an all out gang war has erupted in New York City, and it's up to Spider-Man to stop it.
A new security cell at Ryker's, codenamed the Vault, opens and Spider-Man offers to be the first test subject. Unfortunately, Green Goblin traps him inside with several villains that he helped put away.
Both Peter Parker and Spider-Man make big decisions: Peter decides to break up with Liz and Spider-Man unmasks the Green Goblin. Unfortunately, nothing goes as planned.
An hour long 'Special' originally released on DVD which is actually made up of the first three episodes from Season 1 spliced together with a small amount of extra footage.