| Name | Type | Role | |
|---|---|---|---|
| John Bishop | Host | ||
| Rizzle Kicks | Guest Star | ||
| Jason Byrne | Guest Star | ||
| Jimmy Carr | Guest Star | ||
| Christopher Dean | Guest Star | ||
| Bryn Terfel | Guest Star | ||
| Mary J. Blige | Guest Star | ||
| Stephen Ward | Guest Star | ||
| Seann Walsh | Guest Star | ||
| Robbie Williams | Guest Star | ||
| Olly Murs | Guest Star | ||
| King Charles III | Guest Star | ||
| Flavia Cacace | Guest Star | ||
| Gary Barlow | Guest Star | ||
| John Newman | Guest Star | ||
| Caro Emerald | Guest Star | ||
| Camilla Parker-Bowles | Guest Star | ||
| Chas & Dave | Guest Star | ||
| Harry Hill | Guest Star | ||
| Jessie J | Guest Star | ||
| Hal Cruttenden | Guest Star | ||
| Jayne Torvill | Guest Star | ||
| Gareth Malone | Guest Star | ||
| Barry Humphries | Guest Star | Dame Edna |