The Round of 32 continues at the 2006 National Heads-Up Championship with Daniel Negreanu taking on Greg Raymer in the Hearts bracket headline match. Meanwhile, it's Phil Laak vs. T.J. Cloutier, David Grey vs. Carlos Mortensen, and Doyle Brunson vs. Shawn Sheikhan to complete the bracket. On the Diamonds side of the bracket, Ted Forrest battles Chad Brown, while it's Paul Phillips vs. Ernie Durack, Barry Shulman vs. Sammy Farha, and Howard Lederer vs. Michael Mizrachi.
| Name | Type | Role | |
|---|---|---|---|
| Gabe Kaplan | Host | Himself - Commentator | |
| Kathryn Tappen | Host | Herself - Commentator | |
| Oliver 'Ali' Nejad | Host | Himself - Tournament MC | |
| Matt Vasgersian | Host | Himself - Commentator |