Jools Holland presents old and new music live from BBC Television Centre. Nick Cave And The Bad Seeds and Jack White's The Raconteurs perform live. Sharleen Spiteri of Texas makes her solo debut showcasing tunes from her forthcoming solo debut Melody, while Wisconsin's Bon Iver, the hotly tipped Scottish outfit Glasvegas and Chatham County Line all perform in the studio. Plus Mary Wilson of The Supremes talks about the Story Of The Supremes exhibition at London's V&A.