James' adventure begins in San Sebastian - a city with 16 Michelin stars - as he experiences pintxos, tries whole-grilled turbot, and samples local cider.
James visits Spain's wine region of La Rioja and a mile-long cellar, eats tapas in the region's capital of Longrono, and explores a Michelin-starred restaurant.
James visits an indoor food market in Bilbao, takes a funicular to a famous steak restaurant, heads to a winery on a seabed and learns how La Carolina is made.
James meets an off-grid family in Asturias, samples fabada stew and Urbies cheese, visits a restaurant famous for its sardines and cooks a steak sandwich.
James visits Vigo, which is home to the biggest fish market in Europe, to try Galician octopus, see how a traditional Galician loaf is made, and visit a furancho.
James tries a calamari sandwich in Madrid, samples garlic prawns, tastes churros, meets a blind food critic, tastes vermouth and cooks chicken in white vermouth.
James visits the local food market in Seville and has breakfast at a secret bar, meets rising culinary star Camilla Furraro, and stops by an orange grove.
James is shown around Cadiz by Jose Pizarro as they visit its food market and Sherry Triangle, eat by the sea, and explore salt flats before cooking at a villa.
James tours Cordoba on an eco tuk tuk as he visits a food market, eats oxtail at a Michelin-starred restaurant, and helps judge a salmorejo competition.
James samples giant tapas in Granada, visits a restaurant with views of the Alhambra, tries pan de Alfacar, goes to an organic caviar farm and cooks steak.
James shops at the local market in Murcia and eats exceptional tapas, is shown how to make caldero, heads to an apricot farm and introduces us to paparajotes.
James visits a rice farm in Valencia, reminisces at a favourite tapas bar of his, enjoys a fishing trip catching blue fin tuna and introduces us to horchata.
James drops by an anchovy producer in Girona, sees how ratafia is made, meets an award-winning chocolatier, visits the Celler de Can Roca and cooks paella.