Kicking off a first-of-its-kind, high-stakes desserts tournament, four chefs compete in a series of chocolate challenges. Spicy booze and a book filled with bonbons are in the mix in round one, and an oversize beverage meets a stinky cheese in the entree basket. The dessert basket features a can of something that could be cause for concern as the chefs make chocolatey showpieces to earn a spot in the grand finale and a shot at the $50,000 prize.