The Heart Diamond, the sole energy source of the underground kingdom called the Diamond Domain, is failing and needs replacing. The only one who can create a new Heart Diamond and save the kingdom is the Pokémon Diancie, the kingdom's Princess, but she does not yet have the power to make one. Diancie goes on a journey to meet the life-giving Legendary Pokémon Xerneas, who will allow Diancie to discover the power to create a Heart Diamond. After months of searching for Xerneas, Diancie goes to explore a city she spotted. She meets the Pokémon trainer Ash Ketchum and his friends, Pikachu, Serena, Clemont, and Bonnie. Ash and his friends join Diancie on her quest to meet Xerneas.
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Ash Ketchum dreams of becoming a Pokémon master. Professor Oak, the local Pokémon researcher, entrusts a Pikachu, the only Pokémon he has left to Ash. Ash does his best to befriend Pikachu, but it refuses to trust him. Only after Ash protects Pikachu from an angry group of Spearows does Pikachu realize how much Ash cares. Along the way, Ash makes many human and Pokémon friends as he works his way through the ranks of the world's many Pokémon Leagues.
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